Ring-opening of oxiranes by silyl-substituted allyl anions. A regiochemical chameleon
- authored by
- Ernst Schaumann, Andreas Kirschning
- Abstract
Lithiated allylsilanes 1 undergo smooth addition to epoxides 4 with variable α, γ regioselectivity yielding the C-silylated enols 5,7 and 6,8, respectively. γ-Selectivity can be successfully enhanced by use of cuprates.
- External Organisation(s)
-
Universität Hamburg
- Type
- Article
- Journal
- Tetrahedron Letters
- Volume
- 29
- Pages
- 4281-4284
- No. of pages
- 4
- ISSN
- 0040-4039
- Publication date
- 1988
- Publication status
- Published
- Peer reviewed
- Yes
- ASJC Scopus subject areas
- Biochemistry, Drug Discovery, Organic Chemistry
- Electronic version(s)
-
https://doi.org/10.1016/S0040-4039(00)80474-8 (Access:
Unknown)