Cobalt-mediated Synthesis of Highly Crowded Steroids
Unusual Observations of Hindered Rotation of a Trimethylsilyl Group
- authored by
- Holger Butenschön, Matthias Winkler, K. Peter C. Vollhardt
- Abstract
(η5-C5H5)Co(CO)2 catalyses the [2+2+2] cycloaddition of silylated enediynes to furnish 1-trimethylsilyl and 1,11-bis(trimethylsilylated) A-ring aromatic steroids which exhibit unexpected hindered rotation of the trimethylsilyl groups.
- External Organisation(s)
-
University of California at Berkeley
- Type
- Article
- Journal
- Journal of the Chemical Society, Chemical Communications
- Pages
- 388-390
- No. of pages
- 3
- ISSN
- 0022-4936
- Publication date
- 1986
- Publication status
- Published
- Peer reviewed
- Yes
- ASJC Scopus subject areas
- Molecular Medicine
- Electronic version(s)
-
https://doi.org/10.1039/C39860000388 (Access:
Unknown)
