In-Plane Phonon Density of States of Li-Graphite Intercalation Compounds

verfasst von
A. Schirmer, J. E. Fischer, P. Heitjans, H. J. Kim, A. Magerl, D. Varnin, H. Zabel
Abstract

The inplane phonon densities of states of Li-graphite intercalation compounds of stage-1 and stage-2 are obtained from neutron time-of-flight spectra. For the stage-2 the ordered compound LiC12 which has the same inplane structure as the stage-1 compound LiCß as well as the dilute compound LiC16 which only reveals short range order were studied. The temperature in the measurements was extended above expected phase transitions for both stages and the density of states is analysed in terms of the effective temperatures T for the inplane vibrational energies. T\\ shows characteristic changes at the thermodynamic temperatures of the phase tansitions. Comparison of the T|| values shows similar inplane dynamics of all Li-compounds at the highest temperatures.

Organisationseinheit(en)
Institut für Physikalische Chemie und Elektrochemie
Externe Organisation(en)
University of Pennsylvania
Ruhr-Universität Bochum
Institut Laue-Langevin
Typ
Artikel
Journal
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
Band
244
Seiten
299-305
Anzahl der Seiten
7
ISSN
1058-725X
Publikationsdatum
04.1994
Publikationsstatus
Veröffentlicht
Peer-reviewed
Ja
ASJC Scopus Sachgebiete
Physik der kondensierten Materie
Elektronische Version(en)
https://doi.org/10.1080/10587259408050121 (Zugang: Unbekannt)